Muon Spin Rotation Studies of Enediynes

Oganesyan, Vasily ORCID:, Cammidge, Andrew N. ORCID:, Hopkins, Gareth A., Cotterill, Fiona M., Reid, Ivan D. and Jayasooriya, Upali A. (2004) Muon Spin Rotation Studies of Enediynes. The Journal of Physical Chemistry A, 108 (10). p. 1860. ISSN 1089-5639

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Muon spin rotation spectra of muoniated radicals of the enediyne compounds (E)- and (Z)-RCCCHCHCCR where R = -CH2CH2CH2CH3 are reported and the temperature variation of these spectra from 250 to 400 K investigated. All primary radicals expected were observed and assigned using ab initio DFT calculations. The properties of a six membered secondary radical likely to be formed by the cyclization of the muoniated Z-isomer were estimated using an ab initio DFT calculation.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
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Depositing User: Rachel Smith
Date Deposited: 31 Jan 2011 16:44
Last Modified: 24 Oct 2022 02:43
DOI: 10.1021/jp0362990

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