Muon spin rotation studies of enediynes

Oganesyan, Vasily S. ORCID: https://orcid.org/0000-0002-8738-1146, Cammidge, Andrew N. ORCID: https://orcid.org/0000-0001-7912-4310, Hopkins, Gareth A., Cotterill, Fiona M., Reid, Ivan D. and Jayasooriya, Upali A. (2004) Muon spin rotation studies of enediynes. The Journal of Physical Chemistry A, 108 (10). pp. 1860-1866. ISSN 1089-5639

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Abstract

Muon spin rotation spectra of muoniated radicals of the enediyne compounds (E)- and (Z)-RCCCHCHCCR where R = -CH2CH2CH2CH3 are reported and the temperature variation of these spectra from 250 to 400 K investigated. All primary radicals expected were observed and assigned using ab initio DFT calculations. The properties of a six membered secondary radical likely to be formed by the cyclization of the muoniated Z-isomer were estimated using an ab initio DFT calculation.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Centre for Photonics and Quantum Science (former - to 2025) Faculty of Science > Research Groups > Chemistry of Light and Energy (former - to 2025) Faculty of Science > Research Groups > Chemistry of Life Processes (former - to 2025) Faculty of Science > Research Centres > Centre for Molecular and Structural Biochemistry Faculty of Science > Research Groups > Biophysical Chemistry (former - to 2017) Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis (former - to 2025) Faculty of Science > Research Groups > Physical and Analytical Chemistry (former - to 2017) Faculty of Science > Research Groups > Synthetic and Medicinal Chemistry
Depositing User:	Rachel Smith
Date Deposited:	31 Jan 2011 16:44
Last Modified:	18 Jun 2026 15:42
URI:	https://ueaeprints.uea.ac.uk/id/eprint/10990
DOI:	10.1021/jp0362990

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