Muon spin rotation studies of enediynes

Oganesyan, Vasily S., Cammidge, Andrew N., Hopkins, Gareth A., Cotterill, Fiona M., Reid, Ivan D. and Jayasooriya, Upali A. (2004) Muon spin rotation studies of enediynes. The Journal of Physical Chemistry A, 108 (10). pp. 1860-1866. ISSN 1089-5639

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Abstract

Muon spin rotation spectra of muoniated radicals of the enediyne compounds (E)- and (Z)-RCCCHCHCCR where R = -CH2CH2CH2CH3 are reported and the temperature variation of these spectra from 250 to 400 K investigated. All primary radicals expected were observed and assigned using ab initio DFT calculations. The properties of a six membered secondary radical likely to be formed by the cyclization of the muoniated Z-isomer were estimated using an ab initio DFT calculation.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Centre for Photonics and Quantum Science Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Chemistry of Life Processes Faculty of Science > Research Centres > Centre for Molecular and Structural Biochemistry Faculty of Science > Research Groups > Biophysical Chemistry (former - to 2017) Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Physical and Analytical Chemistry (former - to 2017)
Depositing User:	Rachel Smith
Date Deposited:	31 Jan 2011 16:44
Last Modified:	06 Feb 2025 03:27
URI:	https://ueaeprints.uea.ac.uk/id/eprint/10990
DOI:	10.1021/jp0362990

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