Structural characterization of a cationic zirconocene dimethylaniline complex and related catalytically relevant species

Wilson, Polly A., Wright, Joseph A. ORCID: https://orcid.org/0000-0001-9603-1001, Oganesyan, Vasily S. ORCID: https://orcid.org/0000-0002-8738-1146, Lancaster, Simon J. and Bochmann, Manfred ORCID: https://orcid.org/0000-0001-7736-5428 (2008) Structural characterization of a cationic zirconocene dimethylaniline complex and related catalytically relevant species. Organometallics, 27 (23). pp. 6371-6374. ISSN 1520-6041

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Abstract

We report the first crystallographically characterized dimethylaniline complex of a group 4 metallocene. [(IPCF)ZrMe(NMe2Ph)][B(C6F5)4] shows strongly coordinated NMe2Ph which does not interchange in solution. DFT calculations suggest that the Zr-N bond is 23 kJ mol-1 stronger than the Zr-Me-Zr bond in [{(IPCF)ZrMe}2(µ-Me)][MeB(C6F5)3], the structure of which is also reported (IPCF = Me2C(C5H4)(fluorenyl)).

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Biophysical Chemistry (former - to 2017) Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis (former - to 2025) Faculty of Science > Research Groups > Chemistry of Light and Energy (former - to 2025) Faculty of Science > Research Groups > Chemistry of Life Processes (former - to 2025) Faculty of Science > Research Centres > Centre for Molecular and Structural Biochemistry Faculty of Science > Research Groups > Energy Materials Laboratory (former - to 2025) Faculty of Science > Research Groups > Centre for Photonics and Quantum Science (former - to 2025) Faculty of Science > Research Groups > Synthetic and Medicinal Chemistry Faculty of Science > Research Groups > Education Research & Practice
Depositing User:	Vishal Gautam
Date Deposited:	02 Nov 2010 17:48
Last Modified:	18 Jun 2026 15:12
URI:	https://ueaeprints.uea.ac.uk/id/eprint/10544
DOI:	10.1021/om800783h

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