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Wilson, Polly A., Wright, Joseph A. 
ORCID: https://orcid.org/0000-0001-9603-1001, Oganesyan, Vasily S. ORCID: https://orcid.org/0000-0002-8738-1146, Lancaster, Simon J. and Bochmann, Manfred ORCID: https://orcid.org/0000-0001-7736-5428
(2008)
Structural characterization of a cationic zirconocene dimethylaniline complex and related catalytically relevant species.
Organometallics, 27 (23).
pp. 6371-6374.
Abstract
We report the first crystallographically characterized dimethylaniline complex of a group 4 metallocene. [(IPCF)ZrMe(NMe2Ph)][B(C6F5)4] shows strongly coordinated NMe2Ph which does not interchange in solution. DFT calculations suggest that the Zr-N bond is 23 kJ mol-1 stronger than the Zr-Me-Zr bond in [{(IPCF)ZrMe}2(µ-Me)][MeB(C6F5)3], the structure of which is also reported (IPCF = Me2C(C5H4)(fluorenyl)).
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry (former - to 2024) |
| UEA Research Groups: | Faculty of Science > Research Groups > Biophysical Chemistry (former - to 2017) Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Chemistry of Life Processes Faculty of Science > Research Centres > Centre for Molecular and Structural Biochemistry Faculty of Science > Research Groups > Energy Materials Laboratory Faculty of Science > Research Groups > Centre for Photonics and Quantum Science |
| Depositing User: | Vishal Gautam |
| Date Deposited: | 02 Nov 2010 17:48 |
| Last Modified: | 24 Sep 2024 09:27 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/10544 |
| DOI: | 10.1021/om800783h |
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