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Sarazin, Yann, Wright, Joseph A. 
ORCID: https://orcid.org/0000-0001-9603-1001, Harding, Duncan A. J., Martin, Eddy, Woodman, Timothy J., Hughes, David L. and Bochmann, Manfred ORCID: https://orcid.org/0000-0001-7736-5428
(2008)
Synthesis and structures of new binuclear zinc alkyl, aryl and aryloxo complexes.
Journal of Organometallic Chemistry, 693 (8-9).
pp. 1494-1501.
Abstract
The synthesis of a series of binuclear zinc complexes with Cl, N and O bridges is reported. The reaction of EtZnCl with B(C6F5)(3) in the presence of hexamethylbenzene affords the arene complex [Zn(mu-Cl)(C6F5)(eta-C6Me6)](2) in which the C6Me6 ligand may be regarded as eta(3)-bonded. The comproportionation of Zn[N(SiMe3)(2)](2) with ZnBu2t or Zn(C6F5)(2) toluene gave [(BuZn)-Zn-t{mu-N(SiMe3)(2)}](2) and [C6F5Zn{mu-N(SiMe3)(2)}](2), respectively, with three-coordinate zinc. The reaction of ZnEt2 with C6F5OH in the presence of pyridine gave [EtZn(mu-OC6F5)(py)](2), while ZnMe2 and C6F5OH followed by recrystallisation from THF gave [Zn(OC6F5)(mu-OC6F5)(THF)(2)](2) with five-coordinate zinc in a trigonal-bipyramidal geometry. The structures of these compounds have been determined. (C) 2007 Elsevier B.V. All rights reserved.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry (former - to 2024) |
| UEA Research Groups: | Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Energy Materials Laboratory |
| Depositing User: | Vishal Gautam |
| Date Deposited: | 02 Nov 2010 17:48 |
| Last Modified: | 24 Sep 2024 09:35 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/10540 |
| DOI: | 10.1016/j.jorganchem.2007.10.043 |
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