Mono(arene) Complexes of Thallium(I) Supported by a Weakly Coordinating Anion

Sarazin, Yann, Kaltsoyannis, Nikolas, Wright, Joseph A. and Bochmann, Manfred (2007) Mono(arene) Complexes of Thallium(I) Supported by a Weakly Coordinating Anion. Organometallics, 26 (7). pp. 1811-1815.

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Abstract

Discrete cationic mono(arene) complexes of thallium(I), [Tl(Cp2Fe)]+ and [Tl(C6Me6)]+, were synthesized as [H2N{B(C6F5)3}2]- salts. The Tl···centroid distance of 2.723 Å to the arene in [Tl(C6Me6)]+ is the shortest described to date. This remarkably strong arene p-bonding is confirmed by DFT calculations, which give a Tl-C6Me6 interaction energy of 163 kJ mol-1.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 02 Nov 2010 17:48
Last Modified: 21 Apr 2020 19:16
URI: https://ueaeprints.uea.ac.uk/id/eprint/10536
DOI: 10.1021/om061154b

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