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Sarazin, Yann, Kaltsoyannis, Nikolas, Wright, Joseph A. 
ORCID: https://orcid.org/0000-0001-9603-1001 and Bochmann, Manfred ORCID: https://orcid.org/0000-0001-7736-5428
(2007)
Mono(arene) complexes of thallium(I) supported by a weakly coordinating anion.
Organometallics, 26 (7).
pp. 1811-1815.
Abstract
Discrete cationic mono(arene) complexes of thallium(I), [Tl(Cp2Fe)]+ and [Tl(C6Me6)]+, were synthesized as [H2N{B(C6F5)3}2]- salts. The Tl···centroid distance of 2.723 Å to the arene in [Tl(C6Me6)]+ is the shortest described to date. This remarkably strong arene p-bonding is confirmed by DFT calculations, which give a Tl-C6Me6 interaction energy of 163 kJ mol-1.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry (former - to 2024) |
| UEA Research Groups: | Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Energy Materials Laboratory |
| Depositing User: | Rachel Smith |
| Date Deposited: | 02 Nov 2010 17:48 |
| Last Modified: | 24 Sep 2024 09:38 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/10536 |
| DOI: | 10.1021/om061154b |
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