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Moreno, Carlos Alonso, Hughes, David L. and Bochmann, Manfred 
ORCID: https://orcid.org/0000-0001-7736-5428
(2007)
Synthesis and molecular structure of [Mg(CH2SiMe3)(μ3-OCH2SiMe3)]4.
Polyhedron, 26 (12).
pp. 2523-2526.
ISSN 1873-3719
Abstract
Crystalline [Mg(CH2SiMe3)(µ3-OCH2SiMe3)]4 has been identified as the product of oxidation of ClMgCH2SiMe3 with traces of O2. Its formation requires the formation of Mg(CH2SiMe3)2 via the Schlenk equilibrium. The compound is a rare example of a structurally characterized magnesium alkyl alkoxide with Mg4O4 cubane structure.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry |
| UEA Research Groups: | Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Chemistry of Materials and Catalysis |
| Depositing User: | Rachel Smith |
| Date Deposited: | 02 Nov 2010 17:48 |
| Last Modified: | 24 Oct 2022 01:11 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/10535 |
| DOI: | 10.1016/j.poly.2006.12.026 |
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