Synthesis and crystal structure of ethyl zinc chloride

Guerrero, Antonio, Hughes, David L. and Bochmann, Manfred (2006) Synthesis and crystal structure of ethyl zinc chloride. Organometallics, 25 (6). pp. 1525-1527. ISSN 1520-6041

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Abstract

Crystalline ethylzinc chloride exists as a coordination polymer in the form of puckered sheets with Zn3Cl3 rings, which differ from the well-known structure of [EtZnI]8 in adopting a boat rather than chair conformation. This contrasts with the tetrameric cubane structure suggested in 1966 based on molecular weight determinations in benzene solution.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User:	Rachel Smith
Date Deposited:	02 Nov 2010 17:48
Last Modified:	28 Mar 2025 03:56
URI:	https://ueaeprints.uea.ac.uk/id/eprint/10522
DOI:	10.1021/om051043x

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