Arylzinc complexes as new initiator systems for the production of isobutene copolymers with high isoprene content

Garratt, Shaun, Guerrero, Antonio, Hughes, David L. and Bochmann, Manfred ORCID: https://orcid.org/0000-0001-7736-5428 (2004) Arylzinc complexes as new initiator systems for the production of isobutene copolymers with high isoprene content. Angewandte Chemie-International Edition, 43 (16). pp. 2166-2169. ISSN 1433-7851

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Abstract

The initiator system [Zn(C6F5)2]/tBuCl for isobutene/isoprene copolymerizations (see scheme) gave products with high molecular weights, significantly increased isoprene incorporation, and minimal cross-linking.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
UEA Research Groups: Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Faculty of Science > Research Groups > Chemistry of Light and Energy
Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User: Rachel Smith
Date Deposited: 02 Nov 2010 17:48
Last Modified: 02 Mar 2023 12:30
URI: https://ueaeprints.uea.ac.uk/id/eprint/10501
DOI: 10.1002/anie.200353787

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