Arylzinc complexes as new initiator systems for the production of isobutene copolymers with high isoprene content

Garratt, Shaun, Guerrero, Antonio, Hughes, David L. and Bochmann, Manfred ORCID: https://orcid.org/0000-0001-7736-5428 (2004) Arylzinc complexes as new initiator systems for the production of isobutene copolymers with high isoprene content. Angewandte Chemie International Edition, 43 (16). pp. 2166-2169. ISSN 1433-7851

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Abstract

The initiator system [Zn(C6F5)2]/tBuCl for isobutene/isoprene copolymerizations (see scheme) gave products with high molecular weights, significantly increased isoprene incorporation, and minimal cross-linking.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User:	Rachel Smith
Date Deposited:	02 Nov 2010 17:48
Last Modified:	02 Apr 2024 00:27
URI:	https://ueaeprints.uea.ac.uk/id/eprint/10501
DOI:	10.1002/anie.200353787

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