Arylzinc complexes as new initiator systems for the production of isobutene copolymers with high isoprene content

Garratt, Shaun, Guerrero, Antonio, Hughes, David L. and Bochmann, Manfred (2004) Arylzinc complexes as new initiator systems for the production of isobutene copolymers with high isoprene content. Angewandte Chemie International Edition, 43 (16). pp. 2166-2169. ISSN 1433-7851

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Abstract

The initiator system [Zn(C6F5)2]/tBuCl for isobutene/isoprene copolymerizations (see scheme) gave products with high molecular weights, significantly increased isoprene incorporation, and minimal cross-linking.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User:	Rachel Smith
Date Deposited:	02 Nov 2010 17:48
Last Modified:	06 Feb 2025 03:21
URI:	https://ueaeprints.uea.ac.uk/id/eprint/10501
DOI:	10.1002/anie.200353787

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