Synthesis and catalytic activity of binuclear titanium imido complexes

Said, Musa, Hughes, David L. and Bochmann, Manfred ORCID: https://orcid.org/0000-0001-7736-5428 (2004) Synthesis and catalytic activity of binuclear titanium imido complexes. Dalton Transactions (3). pp. 359-360. ISSN 1477-9234

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Abstract

Treatment of the N–P ligand ArPN(SiMe3)2 with TiCl4 affords the imido-bridged binuclear titanium complex [TiCl2(THF)(µ-NArP)]2(ArP=m-C6H4PR2) which reacts with Ni(0) or Pd(II) to give heterotrinuclear compounds, while activation with methylaluminoxane generates a new type of imido-based ethene polymerisation catalyst that is tolerant of –PR2 functional groups.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User:	Rachel Smith
Date Deposited:	02 Nov 2010 17:48
Last Modified:	06 Mar 2023 12:30
URI:	https://ueaeprints.uea.ac.uk/id/eprint/10500
DOI:	10.1039/b315711c

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