Synthesis and catalytic activity of binuclear titanium imido complexes

Said, Musa, Hughes, David L. and Bochmann, Manfred (2004) Synthesis and catalytic activity of binuclear titanium imido complexes. Dalton Transactions (3). pp. 359-360. ISSN 1477-9234

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Abstract

Treatment of the N–P ligand ArPN(SiMe3)2 with TiCl4 affords the imido-bridged binuclear titanium complex [TiCl2(THF)(µ-NArP)]2(ArP=m-C6H4PR2) which reacts with Ni(0) or Pd(II) to give heterotrinuclear compounds, while activation with methylaluminoxane generates a new type of imido-based ethene polymerisation catalyst that is tolerant of –PR2 functional groups.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User:	Rachel Smith
Date Deposited:	02 Nov 2010 17:48
Last Modified:	06 Feb 2025 03:22
URI:	https://ueaeprints.uea.ac.uk/id/eprint/10500
DOI:	10.1039/b315711c

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