Pennington, Dale A., Hughes, David L., Bochmann, Manfred ORCID: https://orcid.org/0000-0001-7736-5428 and Lancaster, Simon J.
(2003)
The synthesis, structure and catalytic activity of mono(salicylaldiminato) titanium complexes.
Dalton Transactions (18).
pp. 3480-3482.
ISSN 1477-9234
Abstract
Reaction between 3-But-2-(OSiMe3)C6H3CH=N(2,6-R2C6H3) (where R = H (1a) or Pri (1b)) and TiCl4(THF)2 affords the octahedral complexes Ti{3-But-2-(O)C6H3CH=N(2,6-R2C6H3)}Cl3(THF) while in the absence of THF 1b reacts with TiCl4 to give the binuclear complex [Ti{3-But-2-(O)C6H3CH=N(2,6-Pri2C6H3)}Cl(µ–Cl)3TiCl3]; the complexes give good productivities for ethene polymerisation when activated with MAO.
Item Type: | Article |
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Faculty \ School: | Faculty of Science > School of Chemistry |
Depositing User: | Rachel Smith |
Date Deposited: | 02 Nov 2010 17:48 |
Last Modified: | 07 Mar 2023 16:30 |
URI: | https://ueaeprints.uea.ac.uk/id/eprint/10494 |
DOI: | 10.1039/b307793b |
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