The synthesis, structure and catalytic activity of mono(salicylaldiminato) titanium complexes

Pennington, Dale A., Hughes, David L., Bochmann, Manfred and Lancaster, Simon J. (2003) The synthesis, structure and catalytic activity of mono(salicylaldiminato) titanium complexes. Dalton Transactions (18). pp. 3480-3482. ISSN 1477-9234

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Abstract

Reaction between 3-But-2-(OSiMe3)C6H3CH=N(2,6-R2C6H3) (where R = H (1a) or Pri (1b)) and TiCl4(THF)2 affords the octahedral complexes Ti{3-But-2-(O)C6H3CH=N(2,6-R2C6H3)}Cl3(THF) while in the absence of THF 1b reacts with TiCl4 to give the binuclear complex [Ti{3-But-2-(O)C6H3CH=N(2,6-Pri2C6H3)}Cl(µ–Cl)3TiCl3]; the complexes give good productivities for ethene polymerisation when activated with MAO.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User:	Rachel Smith
Date Deposited:	02 Nov 2010 17:48
Last Modified:	06 Feb 2025 03:31
URI:	https://ueaeprints.uea.ac.uk/id/eprint/10494
DOI:	10.1039/b307793b

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