The synthesis, structure and catalytic activity of mono(salicylaldiminato) titanium complexes

Pennington, Dale A., Hughes, David L., Bochmann, Manfred ORCID: https://orcid.org/0000-0001-7736-5428 and Lancaster, Simon J. (2003) The synthesis, structure and catalytic activity of mono(salicylaldiminato) titanium complexes. Dalton Transactions (18). pp. 3480-3482. ISSN 1477-9234

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Abstract

Reaction between 3-But-2-(OSiMe3)C6H3CH=N(2,6-R2C6H3) (where R = H (1a) or Pri (1b)) and TiCl4(THF)2 affords the octahedral complexes Ti{3-But-2-(O)C6H3CH=N(2,6-R2C6H3)}Cl3(THF) while in the absence of THF 1b reacts with TiCl4 to give the binuclear complex [Ti{3-But-2-(O)C6H3CH=N(2,6-Pri2C6H3)}Cl(µ–Cl)3TiCl3]; the complexes give good productivities for ethene polymerisation when activated with MAO.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017)
Depositing User:	Rachel Smith
Date Deposited:	02 Nov 2010 17:48
Last Modified:	07 Mar 2023 16:30
URI:	https://ueaeprints.uea.ac.uk/id/eprint/10494
DOI:	10.1039/b307793b

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