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Lancaster, Simon J. and Bochmann, Manfred 
ORCID: https://orcid.org/0000-0001-7736-5428
(2002)
The reaction of Cp*2ZrMe2 with [CPh3][B(C6F5)4]: triphenylethane does not form ηn-arene complexes with [Cp*2ZrMe]+.
Journal of Organometallic Chemistry, 654 (1-2).
pp. 221-223.
Abstract
In response to a recent paper concerning the formation of a putative arene complex, [Cp*2Zr(CH3)?-C6H5C(C6H5)2CH3][B(C6F5)4] from the reaction of Cp*2ZrMe2 with [CPh3][B(C6F5)4] in CD2Cl2 at -78 °C, we present data showing that this reaction leads in fact to a mixture of [(Cp*2ZrMe)2(µ-Me)][B(C6F5)4] and [Cp*2ZrMe...B(C6F5)4], while NMR signals attributed to ?-arene coordination of triphenylethane are due to unreacted CPh3+ (Cp*=?-C5Me5).
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry (former - to 2024) |
| UEA Research Groups: | Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy |
| Depositing User: | Rachel Smith |
| Date Deposited: | 02 Nov 2010 17:48 |
| Last Modified: | 24 Sep 2024 10:14 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/10482 |
| DOI: | 10.1016/S0022-328X(02)01319-0 |
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