B(C6F5)3 as aC6F5 transfer reagent in zirconium chemistry: facileformation of the borole-bridged triple-decker complex[Zr2Cp″2(C6F5)2{μ-η5∶η5-C4H4BCH2-η3,κF-CHCHCHB(C6F5)3}]

Woodman, Timothy J., Thornton-Pett, Mark and Bochmann, Manfred ORCID: https://orcid.org/0000-0001-7736-5428 (2001) B(C6F5)3 as aC6F5 transfer reagent in zirconium chemistry: facileformation of the borole-bridged triple-decker complex[Zr2Cp″2(C6F5)2{μ-η5∶η5-C4H4BCH2-η3,κF-CHCHCHB(C6F5)3}]. Chemical Communications (4). pp. 329-330. ISSN 1364-548X

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Abstract

Warming mixtures of (CpR)Zr(?3-C4H7)(? 4-C4H6) and B(C6F5)3 leads to complete transfer of all three C6F5 substituents of a B(C6F5)3 molecule to give borole-bridged triple-decker complexes with a Zr2C4B core, a zwitterionic structure and an unusually strong Zr–F donor interaction.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User:	Rachel Smith
Date Deposited:	02 Nov 2010 17:48
Last Modified:	24 Oct 2022 03:31
URI:	https://ueaeprints.uea.ac.uk/id/eprint/10473
DOI:	10.1039/b009016f

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