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Men, S., Lovelock, K.R.J. and Licence, P. 
ORCID: https://orcid.org/0000-0003-2992-0153
(2017)
X-ray photoelectron spectroscopy of trihalide ionic liquids: Comparison to halide-based analogues, anion basicity and beam damage.
Chemical Physics Letters.
ISSN 0009-2614
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Abstract
X-ray photoelectron spectroscopy is used to investigate two 1-octyl-3-methylimidazolium trihalide ionic liquids, with anions including triiodide and iododibromide. The electronic environment of each element present in ionic liquids studied herein is analysed and compared to their halide-based analogous. The anion basicity is compared based upon the measured N 1s binding energy. The iododibromide ionic liquid is studied as a representative sample to illustrate the beam damage effect. Due to the beam damage, there is a new formed bromine component observed. This effect is calculated and demonstrated for all elements present within the ionic liquid. It suggests that the beam induced decomposition caused a stoichiometric loss of bromine atom and iodine atom.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry, Pharmacy and Pharmacology |
| Related URLs: | |
| Depositing User: | LivePure Connector |
| Date Deposited: | 01 Oct 2026 10:12 |
| Last Modified: | 06 Oct 2026 23:26 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/104696 |
| DOI: | 10.1016/j.cplett.2017.05.010 |
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