Divergent Mechanisms for the Skeletal Rearrangement and [2+2] Cycloaddition of Enynes Catalyzed by Gold

Nieto-Oberhuber, Cristina, López, Salomé, Munoz-Herranz, Maria, Cárdenas, Diego J., Buñuel, Elena, Nevado, Cristina and Echavarren, Antonio M. (2005) Divergent Mechanisms for the Skeletal Rearrangement and [2+2] Cycloaddition of Enynes Catalyzed by Gold. Angewandte Chemie-International Edition, 44 (38). pp. 6146-6148. ISSN 1433-7851

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Abstract

Support for the direct route: That cyclobutenes are not necessary intermediates in the skeletal rearrangement of enynes is supported by DFT calculations and kinetic studies. Cyclobutenes may arise from the corresponding syn-cyclopropylgold(I) carbenes

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
University of East Anglia > Faculty of Science > Research Groups > Synthetic Chemistry
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Depositing User: Rachel Smith
Date Deposited: 14 Feb 2012 16:20
Last Modified: 25 Jul 2018 06:36
URI: https://ueaeprints.uea.ac.uk/id/eprint/37112
DOI: 10.1002/anie.200501937

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