Unexpected nucleophilic participation and rearrangement of DBU in reactions with saccharin derivatives

Bulman Page, Philip C., Vahedi, Hooshang, Bethell, Donald and Barkley, James V. (2003) Unexpected nucleophilic participation and rearrangement of DBU in reactions with saccharin derivatives. Synthetic Communications, 33 (11). pp. 1937-1941. ISSN 0039-7911

Preview

PDF (hoosh_DBU_reprint.pdf) - Published Version Download (176kB) | Preview

Abstract

DBU attacks saccharin derivatives with subsequent rearrangement to give rise to 3-[3'-(1"-azepin-2"-onyl)propylamino]-1,2-benzisothiazole-1,1-dioxide 2 after work-up.

Item Type:	Article
Uncontrolled Keywords:	hydrogen-peroxide,dbu,nucleophile,sulfides,catalytic asymmetric oxidation
Faculty \ School:	Faculty of Science > School of Chemistry
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User:	Rachel Smith
Date Deposited:	21 Jun 2011 09:42
Last Modified:	24 Oct 2022 02:53
URI:	https://ueaeprints.uea.ac.uk/id/eprint/32851
DOI:	10.1081/scc-120020208

Downloads

Actions (login required)

View Item