Electrophilic amination of ketone enolates mediated by the DiTOX asymmetric building block: Enantioselective formal synthesis of alpha-aminoacids

Bulman Page, Philip C.., McKenzie, Michael J., Allin, Steven M. and Buckle, Derek R. (2000) Electrophilic amination of ketone enolates mediated by the DiTOX asymmetric building block: Enantioselective formal synthesis of alpha-aminoacids. Tetrahedron, 56 (49). pp. 9683-9695. ISSN 0040-4020

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Abstract

Diastereoselective electrophilic amination of enolates derived from 2-acyl-1,3-dithiane 1-oxides is used as the key step for an enantioselective synthesis of two alpha -hydrazido carboxylic acids, well-known precursors of alpha -amino acids. (C) 2000 Elsevier Science Ltd. All rights reserved.

Item Type: Article
Uncontrolled Keywords: arylglycines,ethers,alkylation,sulfoxidation,esters,hydrazino acids,chiral auxiliary,3-dithiane 1-oxides,acid-derivatives,1,asymmetric synthesis,aminoacid,stereoselective amination,enolate,azodicarboxylate
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Rachel Smith
Date Deposited: 21 Jun 2011 12:45
Last Modified: 05 Apr 2019 14:30
URI: https://ueaeprints.uea.ac.uk/id/eprint/32812
DOI: 10.1016/S0040-4020(00)00923-6

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