Aryl trihydroxyborates: Easily isolated discrete species convenient for direct application in coupling reactions

Cammidge, Andrew N. ORCID: https://orcid.org/0000-0001-7912-4310, Goddard, Victoria H. M., Gopee, Hemant, Harrison, Nicola L., Hughes, David L., Schubert, Christopher J., Sutton, Benjamin M., Watts, Gary L. and Whitehead, Andrew J. (2006) Aryl trihydroxyborates: Easily isolated discrete species convenient for direct application in coupling reactions. Organic Letters, 8 (18). pp. 4071-4074. ISSN 1523-7052

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Abstract

A conceptually and practically simple alternative approach to the use of arylboron species as the organometallic component in cross-coupling processes is described whereby trihydroxyborate salts are isolated and directly employed. The protocol derives practical benefit from the ease and convenience of the isolation and subsequent use of the discrete borate salts, eliminates the need for additional base, and aids the use of correct reaction stoichiometry.

Item Type:	Article
Uncontrolled Keywords:	sdg 3 - good health and well-being ,/dk/atira/pure/sustainabledevelopmentgoals/good_health_and_well_being
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024) Faculty of Science > School of Chemical Sciences and Pharmacy (former - to 2009)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy
Depositing User:	Rachel Smith
Date Deposited:	09 May 2011 14:37
Last Modified:	24 Sep 2024 09:47
URI:	https://ueaeprints.uea.ac.uk/id/eprint/30048
DOI:	10.1021/ol061564w

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