Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

Ibrahim, Saad, Woi, Pei Meng, Alias, Yatimah and Pickett, Christopher (2010) Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix. Chemical Communications, 46 (43). pp. 8189-8191. ISSN 1364-548X

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Abstract

We show that a redox active {Fe4S4}2+–cubane assembly covalently bound within a cysteinyl–alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
University of East Anglia > Faculty of Science > Research Groups > Biophysical Chemistry
University of East Anglia > Faculty of Science > Research Groups > Synthetic Chemistry
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Depositing User: Rachel Smith
Date Deposited: 23 Mar 2011 16:05
Last Modified: 25 Jul 2018 04:24
URI: https://ueaeprints.uea.ac.uk/id/eprint/27072
DOI: 10.1039/c0cc02962a

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