The synthesis, structure and catalytic activity of mono(salicylaldiminato) titanium complexes

Pennington, DA, Hughes, DL, Bochmann, M and Lancaster, SJ (2003) The synthesis, structure and catalytic activity of mono(salicylaldiminato) titanium complexes. Dalton Transactions (18). pp. 3480-3482.

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Abstract

Reaction between 3-But-2-(OSiMe3)C6H3CH=N(2,6-R2C6H3) (where R = H (1a) or Pri (1b)) and TiCl4(THF)2 affords the octahedral complexes Ti{3-But-2-(O)C6H3CH=N(2,6-R2C6H3)}Cl3(THF) while in the absence of THF 1b reacts with TiCl4 to give the binuclear complex [Ti{3-But-2-(O)C6H3CH=N(2,6-Pri2C6H3)}Cl(µ–Cl)3TiCl3]; the complexes give good productivities for ethene polymerisation when activated with MAO.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
University of East Anglia > Faculty of Science > Research Groups > Synthetic Chemistry
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Depositing User: Rachel Smith
Date Deposited: 02 Nov 2010 17:48
Last Modified: 28 Aug 2018 14:31
URI: https://ueaeprints.uea.ac.uk/id/eprint/10494
DOI: 10.1039/b307793b

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