Epoxide formation in the Friedel-Crafts reaction of adipoyl chloride and bromobenzene

Cammidge, Andrew N. ORCID: https://orcid.org/0000-0001-7912-4310, Kelsey, Richard D. and King, Amy S. H. (1999) Epoxide formation in the Friedel-Crafts reaction of adipoyl chloride and bromobenzene. Tetrahedron Letters, 40 (1). pp. 147-148. ISSN 0040-4039

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Abstract

The aluminium chloride catalysed Friedel-Crafts reaction between adipoyl chloride and bromobenzene has been re-examined. At elevated temperatures a number of side products are produced including a cyclopentane epoxide. The structure of this epoxide was elucidated by nmr and ir spectroscopy and its stereochemistry confirmed by x-ray crystallography.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Centre for Photonics and Quantum Science (former - to 2025) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis (former - to 2025) Faculty of Science > Research Groups > Chemistry of Light and Energy (former - to 2025) Faculty of Science > Research Groups > Synthetic and Medicinal Chemistry
Depositing User:	LivePure Connector
Date Deposited:	25 Jul 2024 08:30
Last Modified:	18 Jun 2026 20:16
URI:	https://ueaeprints.uea.ac.uk/id/eprint/96013
DOI:	10.1016/S0040-4039(98)80043-9

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