Redox-catalysis flow electrode desalination in an organic solvent

Wei, Qiang, Tang, Lufan, Ramalingam, Karthick, Liang, Mengjun, Ma, Jinxing, Shi, Yumeng, Hui, Kwun Nam, Hui, Kwan San ORCID: and Chen, Fuming (2021) Redox-catalysis flow electrode desalination in an organic solvent. Journal of Materials Chemistry A, 9 (39). pp. 22254-22261. ISSN 2050-7488

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The typical flow electrode capacitive deionization (FCDI) device uses carbon materials as flow electrodes in aqueous conditions. The low salt removal rate and high energy consumption have hindered further development. In this study, we propose an organic redox flow electrode in FCDI to achieve a quick salt removal process and low energy consumption. The organic medium, i.e., acetonitrile, containing 50 mM NaI/30 mM I2 electrolyte as the redox couples replaces the conventional water-based electrolyte. With the addition of 3 wt% multi-wall carbon nanotubes with the –NH2 group, the highest desalination rate of 6.8 μg cm−2 s−1 could be achieved at a current density of 13 mA cm−2, which is the highest desalination rate in capacitive deionization systems applied to date. Furthermore, the electrical energy consumption is reduced to zero when using the light illumination on the semiconductor as the driving force. The high-performance FCDI device based on the organic redox electrodes is of great significance for the practical desalination application at a low energy cost.

Item Type: Article
Faculty \ School: Faculty of Science > School of Engineering
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Depositing User: LivePure Connector
Date Deposited: 24 Nov 2021 03:12
Last Modified: 23 Oct 2022 03:13
DOI: 10.1039/D1TA05350G

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