A novel one-dimensional coordination polymer with Cd2+ and diethylene-triaminepentaacetic acid

Almeida Paz, Filipe A., Bond, Andrew D., Khimyak, Y. Z. and Klinowski, Jacek (2002) A novel one-dimensional coordination polymer with Cd2+ and diethylene-triaminepentaacetic acid. Acta Crystallographica Section C: Crystal Structure Communications, 58 (12). m608-m610. ISSN 0108-2701

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Abstract

catena-Poly[[[bis[diaqua(4,4′-bipyridine)cadmium(II)]-bis[μ -(N″-carboxymethyldiethylenetriamine-N,N,N′, N″-tetraacetato) cadmium(II)]]-μ-4,4′-bipyridine] tetradecahydrate], [Cd4(C14H19N3 O10)2(C10 H8N2)3 (H2O)4]· 14H2O or [Cd4(HDTPA)2(BPY)3 (H2O)4]·14H2O, where BPY is 4, 4′bipyridine and HDTPA4- is N″-carboxymethyldiethylenetriamine-N,N,-N′,N″-tetraacetate, consists of a one-dimensional coordination polymer formed from a secondary building unit which comprises four Cd centres. The chain structure of the title compound was obtained by the use of a multidentate organic ligand. N,N,N′,N″,N″-diethylenetriaminepentaacetic acid (H5DTPA), which forms multiple chelate rings with the Cd metal centres. An extended network is formed via hydrogen bonds.

Item Type: Article
Uncontrolled Keywords: biochemistry, genetics and molecular biology(all) ,/dk/atira/pure/subjectarea/asjc/1300
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Depositing User: LivePure Connector
Date Deposited: 09 Jul 2021 07:28
Last Modified: 09 Jul 2021 07:28
URI: https://ueaeprints.uea.ac.uk/id/eprint/80466
DOI: 10.1107/S0108270102019960

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