Solid-state NMR studies of MCM-41 supported with a highly catalytically active cluster

Jones, Matthew D., Duer, Melinda J., Hermans, Sophie, Khimyak, Yaroslav Z., Johnson, Brian F. G. and Meurig Thomas, John (2002) Solid-state NMR studies of MCM-41 supported with a highly catalytically active cluster. Angewandte Chemie - International Edition, 41 (24). pp. 4726-4729. ISSN 1433-7851

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Abstract

New insight into the binding modes of bimetallic clusters and catalytically active nanoparticles to the mesoporous solid MCM-41 has been obtained from solid-state NMR spectroscopic data (see figure, right). From this study, a model has been proposed to explain the interactions between the pore walls and the cluster. It has been shown that the counterion plays an important role in the anchoring process (see figure, left).

Item Type: Article
Uncontrolled Keywords: bimetallic clusters,heterogeneous catalysis,mesoporous materials,nmr spectroscopy,catalysis,chemistry(all) ,/dk/atira/pure/subjectarea/asjc/1500/1503
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Depositing User: LivePure Connector
Date Deposited: 09 Jul 2021 07:28
Last Modified: 30 Sep 2021 16:37
URI: https://ueaeprints.uea.ac.uk/id/eprint/80465
DOI: 10.1002/anie.200290029

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