Bis(4,4′-bipyridine)tetraaquacobalt(II) 2,6-naphathalenedicarboxylate dihydrate

Almeida Paz, Filipe A., Khimyak, Yaroslav Z. and Klinowski, Jacek (2003) Bis(4,4′-bipyridine)tetraaquacobalt(II) 2,6-naphathalenedicarboxylate dihydrate. Acta Crystallographica Section E: Structure Reports Online, 59 (1). m8-m10. ISSN 1600-5368

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Abstract

The title compound, [Co(C10H8N2) 2(H2O)4](C12H6O 4)·2H2O (where C10H8N 2 is 4,4′-bipyridine, BPY, and C12H 6O4 is 2,6-naphthalenedicarboxylate, NDC2-), (CUmof-6), was synthesized under mild hydrothermal conditions. The structure contains [Co(BPY)2(H2O)4]2+ complex cations, which stack along the a axis through close face-to-face contacts. Uncoordinated NDC2- anions are strongly hydrogen bonded to the complex cations. The Co2+ cation and the centre of gravity of NDC2- are located on crystallographic centres of symmetry.

Item Type: Article
Uncontrolled Keywords: chemistry(all),materials science(all),condensed matter physics ,/dk/atira/pure/subjectarea/asjc/1600
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Depositing User: LivePure Connector
Date Deposited: 09 Jul 2021 07:28
Last Modified: 30 Sep 2021 16:37
URI: https://ueaeprints.uea.ac.uk/id/eprint/80463
DOI: 10.1107/S1600536802022122

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