NaSn2(PO4)3 submicro-particles for high performance Na/Li mixed-ion battery anodes

Zhao, Beibei, Zhang, Xudong, Xu, Guogang, San Hui, Kwan ORCID: https://orcid.org/0000-0001-7089-7587, Zhu, Jiefang and He, Wen (2020) NaSn2(PO4)3 submicro-particles for high performance Na/Li mixed-ion battery anodes. Journal of Alloys and Compounds, 844. ISSN 0925-8388

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Abstract

NaSn2(PO4)3 has open framework, high ionic conductivity, low working potential, high theoretical capacity more than twice of graphite. However, its commercial application is limited by its low electrical conductivity and rapid capacity fading. To overcome this challenge, we synthesize NaSn2(PO4)3 submicro-particles (around 100–300 nm in size) by hydrothermally assisted pyrolysis reactions. The synthesized NaSn2(PO4)3 anode for Na/Li mixed-ion batteries delivers an ultrahigh initial discharge capacities, excellent rate performance and superior cycling stability. This design provides a promising pathway for developing high performance mixed-ion batteries.

Item Type: Article
Uncontrolled Keywords: electrochemistry,ionic conductors,lithium-ion batteries,li mixed-ion diffusion,mechanics of materials,mechanical engineering,metals and alloys,materials chemistry,sdg 7 - affordable and clean energy ,/dk/atira/pure/subjectarea/asjc/2200/2211
Faculty \ School: Faculty of Science > School of Engineering
UEA Research Groups: Faculty of Science > Research Groups > Emerging Technologies for Electric Vehicles (EV)
Faculty of Science > Research Groups > Energy Materials Laboratory
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Depositing User: LivePure Connector
Date Deposited: 01 Jul 2020 00:00
Last Modified: 20 Apr 2023 17:30
URI: https://ueaeprints.uea.ac.uk/id/eprint/75844
DOI: 10.1016/j.jallcom.2020.156082

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