Straightforward and controlled synthesis of porphyrin-phthalocyanine-porphyrin heteroleptic triple-decker assemblies

Gonzalez Lucas, Daniel, Soobrattee, Shazia, Hughes, David, Tizzard, Graham J., Coles, Simon J. and Cammidge, Andy (2020) Straightforward and controlled synthesis of porphyrin-phthalocyanine-porphyrin heteroleptic triple-decker assemblies. Chemistry - A European Journal, 26 (47). pp. 10724-10728. ISSN 0947-6539

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Abstract

A versatile and straightforward protocol is disclosed for controlled synthesis of complex lanthanide-bridged heteroleptic porphyrin–phthalocyanine triple-decker assemblies. Two porphyrins, linked by a flexible spacer chain of intermediate length, sequentially capture lanthanide ions and a phthalocyanine to efficiently form the triple-decker complex. The bridge directs assembly, but also controls the mobility of the central macrocycle and further imparts a fully eclipsed arrangement of all three rings.

Item Type: Article
Uncontrolled Keywords: pigments,porphyrinoids,phthalocyanines,lanthanides,synthesis
Faculty \ School: Faculty of Science > School of Chemistry
Faculty of Science
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Depositing User: LivePure Connector
Date Deposited: 28 May 2020 00:20
Last Modified: 18 Sep 2020 23:51
URI: https://ueaeprints.uea.ac.uk/id/eprint/75317
DOI: 10.1002/chem.202002500

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