Straightforward and controlled synthesis of porphyrin-phthalocyanine-porphyrin heteroleptic triple-decker assemblies

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Gonzalez Lucas, Daniel, Soobrattee, Shazia, Hughes, David, Tizzard, Graham J., Coles, Simon J. and Cammidge, Andy ORCID: https://orcid.org/0000-0001-7912-4310 (2020) Straightforward and controlled synthesis of porphyrin-phthalocyanine-porphyrin heteroleptic triple-decker assemblies. Chemistry - A European Journal, 26 (47). pp. 10724-10728. ISSN 0947-6539

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Abstract

A versatile and straightforward protocol is disclosed for controlled synthesis of complex lanthanide-bridged heteroleptic porphyrin–phthalocyanine triple-decker assemblies. Two porphyrins, linked by a flexible spacer chain of intermediate length, sequentially capture lanthanide ions and a phthalocyanine to efficiently form the triple-decker complex. The bridge directs assembly, but also controls the mobility of the central macrocycle and further imparts a fully eclipsed arrangement of all three rings.

Item Type:	Article
Uncontrolled Keywords:	pigments,porphyrinoids,phthalocyanines,lanthanides,synthesis
Faculty \ School:	Faculty of Science > School of Chemistry Faculty of Science
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy
Related URLs:	http://www.scopus.com/inward/record.url?...
Depositing User:	LivePure Connector
Date Deposited:	28 May 2020 00:20
Last Modified:	12 May 2023 09:33
URI:	https://ueaeprints.uea.ac.uk/id/eprint/75317
DOI:	10.1002/chem.202002500

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