Highly efficient blue organic light-emitting diodes based on carbene-metal-amides

Conaghan, Patrick, Matthews, Campbell, Chotard, Florian, Jones, Saul, Greenham, Neil, Bochmann, Manfred ORCID: https://orcid.org/0000-0001-7736-5428, Credgington, Dan and Romanov, Alexander (2020) Highly efficient blue organic light-emitting diodes based on carbene-metal-amides. Nature Communications, 11 (1). ISSN 2041-1723

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Carbene-metal-amides are soluble and thermally stable materials which have recently emerged as emitters in high-performance organic light-emitting diodes. Here we synthesise carbene-metal-amide photoemitters with CF3-substituted ligands to show sky-blue to deep-blue photoluminescence from charge-transfer excited states. We demonstrate that the emission colour can be adjusted from blue to yellow and observe that the relative energies of charge transfer and locally excited triplet states influence the performance of the deep-blue emission. High thermal stability and insensitivity to aggregation-induced luminescence quenching allow us to fabricate organic light-emitting diodes in both host-free and host-guest architectures. We report blue devices with a peak external quantum efficiency of 17.3% in a host-free emitting layer and 20.9% in a polar host. Our findings inform the molecular design of the next generation of stable blue carbene-metal-amide emitters.

Item Type: Article
Uncontrolled Keywords: gold complex,photoemitter,oled
Faculty \ School: Faculty of Science > School of Chemistry
UEA Research Groups: Faculty of Science > Research Groups > Chemistry of Light and Energy
Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
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Depositing User: LivePure Connector
Date Deposited: 22 Apr 2020 08:48
Last Modified: 29 Jun 2023 12:30
URI: https://ueaeprints.uea.ac.uk/id/eprint/74809
DOI: 10.1038/s41467-020-15369-8

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