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Liu, Shude, Yin, Ying, Shen, Yang, Hui, Kwan San 
ORCID: https://orcid.org/0000-0001-7089-7587, Chun, Young Tea, Kim, Jong Min, Hui, Kwun Nam, Zhang, Lipeng and Jun, Seong Chan
(2020)
Phosphorus regulated cobalt oxide@nitrogen-doped carbon nanowires for flexible quasi-solid-state supercapacitors.
Small, 16 (4).
ISSN 1613-6810
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Abstract
Battery-type materials are promising candidates for achieving high specific capacity for supercapacitors. However, their slow reaction kinetics hinders the improvement in electrochemical performance. Herein, a hybrid structure of P-doped Co3 O4 (P-Co3 O4 ) ultrafine nanoparticles in situ encapsulated into P, N co-doped carbon (P, N-C) nanowires by a pyrolysis-oxidation-phosphorization of 1D metal-organic frameworks derived from Co-layered double hydroxide as self-template and reactant is reported. This hybrid structure prevents active material agglomeration and maintains a 1D oriented arrangement, which exhibits a large accessible surface area and hierarchically porous feature, enabling sufficient permeation and transfer of electrolyte ions. Theoretical calculations demonstrate that the P dopants in P-Co3 O4 @P, N-C could reduce the adsorption energy of OH- and regulate the electrical properties. Accordingly, the P-Co3 O4 @P, N-C delivers a high specific capacity of 669 mC cm-2 at 1 mA cm-2 and an ultralong cycle life with only 4.8% loss over 5000 cycles at 30 mA cm-2 . During the fabrication of P-Co3 O4 @P, N-C, Co@P, N-C is simultaneously developed, which can be integrated with P-Co3 O4 @P, N-C for the assembly of asymmetric supercapacitors. These devices achieve a high energy density of 47.6 W h kg-1 at 750 W kg-1 and impressive flexibility, exhibiting a great potential in practical applications.
| Item Type: | Article |
|---|---|
| Additional Information: | © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| Uncontrolled Keywords: | co3o4,efficient,evolution,graphene oxide,high-energy,hybrid supercapacitor,nanotube arrays,ni foam,oxygen reduction,performance,anion regulation,encapsulated hybrids,flexible quasi-solid-state supercapacitors,in situ structural reconstruction,orientated metal organic frameworks |
| Faculty \ School: | Faculty of Science > School of Engineering |
| UEA Research Groups: | Faculty of Science > Research Groups > Emerging Technologies for Electric Vehicles (EV) Faculty of Science > Research Groups > Energy Materials Laboratory |
| Related URLs: | |
| Depositing User: | LivePure Connector |
| Date Deposited: | 04 Feb 2020 04:43 |
| Last Modified: | 20 Apr 2023 12:30 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/73959 |
| DOI: | 10.1002/smll.201906458 |
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