Platinum and Gold Catalysis: à la Carte Hydroamination of Terminal Activated Allenes with Azoles

Alonso, José Miguel and Munoz-Herranz, Maria Paz (2019) Platinum and Gold Catalysis: à la Carte Hydroamination of Terminal Activated Allenes with Azoles. Organic Letters, 21 (18). pp. 7639-7644. ISSN 1523-7060

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Abstract

Nucleophilic additions to allenes catalyzed by transition metals represent a powerful tool to get selective access to diverse structures with numerous applications. Reported here is a straightforward methodology to achieve selective addition of azoles to the proximal or distal carbon of activated allenes depending on the catalyst used, unravelling a gold-platinum bimetallic catalysis approach for the 1,3-double addition of azoles to activated allenes to give 1,3-bisazole derivatives, important scaf-fold in medicinal and organometallic chemistry.

Item Type: Article
Uncontrolled Keywords: allenes,azoles,bimetallic catalysis,gold,platinum,organic chemistry ,/dk/atira/pure/subjectarea/asjc/1600/1605
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: LivePure Connector
Date Deposited: 30 Aug 2019 11:30
Last Modified: 11 Jun 2020 01:14
URI: https://ueaeprints.uea.ac.uk/id/eprint/72065
DOI: 10.1021/acs.orglett.9b02949

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