Alonso, José Miguel and Munoz-Herranz, Maria Paz ORCID: https://orcid.org/0000-0001-9037-349X
(2019)
Platinum and gold catalysis: à la carte hydroamination of terminal activated allenes with azoles.
Organic Letters, 21 (18).
pp. 7639-7644.
ISSN 1523-7060
Preview |
PDF (Organic Letters_azoles a la carte - final revision accepted)
- Accepted Version
Download (519kB) | Preview |
Abstract
Nucleophilic additions to allenes catalyzed by transition metals represent a powerful tool to get selective access to diverse structures with numerous applications. Reported here is a straightforward methodology to achieve selective addition of azoles to the proximal or distal carbon of activated allenes depending on the catalyst used, unravelling a gold-platinum bimetallic catalysis approach for the 1,3-double addition of azoles to activated allenes to give 1,3-bisazole derivatives, important scaf-fold in medicinal and organometallic chemistry.
Item Type: | Article |
---|---|
Uncontrolled Keywords: | allenes,azoles,bimetallic catalysis,gold,platinum,organic chemistry ,/dk/atira/pure/subjectarea/asjc/1600/1605 |
Faculty \ School: | Faculty of Science > School of Chemistry |
Depositing User: | LivePure Connector |
Date Deposited: | 30 Aug 2019 11:30 |
Last Modified: | 22 Oct 2022 05:10 |
URI: | https://ueaeprints.uea.ac.uk/id/eprint/72065 |
DOI: | 10.1021/acs.orglett.9b02949 |
Actions (login required)
![]() |
View Item |