Platinum and Gold Catalysis: à la Carte Hydroamination of Terminal Activated Allenes with Azoles
Alonso, José Miguel and Munoz-Herranz, Maria Paz (2019) Platinum and Gold Catalysis: à la Carte Hydroamination of Terminal Activated Allenes with Azoles. Organic Letters, 21 (18). pp. 7639-7644. ISSN 1523-7060
![]()
|
PDF (Organic Letters_azoles a la carte - final revision accepted)
- Submitted Version
Download (519kB) | Preview |
Abstract
Nucleophilic additions to allenes catalyzed by transition metals represent a powerful tool to get selective access to diverse structures with numerous applications. Reported here is a straightforward methodology to achieve selective addition of azoles to the proximal or distal carbon of activated allenes depending on the catalyst used, unravelling a gold-platinum bimetallic catalysis approach for the 1,3-double addition of azoles to activated allenes to give 1,3-bisazole derivatives, important scaf-fold in medicinal and organometallic chemistry.
Item Type: | Article |
---|---|
Uncontrolled Keywords: | allenes,azoles,bimetallic catalysis,gold,platinum,organic chemistry ,/dk/atira/pure/subjectarea/asjc/1600/1605 |
Faculty \ School: | Faculty of Science > School of Chemistry |
Depositing User: | LivePure Connector |
Date Deposited: | 30 Aug 2019 11:30 |
Last Modified: | 24 Feb 2021 00:54 |
URI: | https://ueaeprints.uea.ac.uk/id/eprint/72065 |
DOI: | 10.1021/acs.orglett.9b02949 |
Actions (login required)
![]() |
View Item |