Rocchigiani, Luca ORCID: https://orcid.org/0000-0002-2679-8407, Jia, Minqiang, Bandini, Marco and Macchioni, Alceo
(2015)
Assessing the role of counterion in gold-catalyzed dearomatization of indoles with allenamides by NMR studies.
ACS Catalysis, 5 (7).
pp. 3911-3915.
ISSN 2155-5435
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Abstract
The counterion effect in the gold(I)-catalyzed dearomative condensation of indoles with allenamides is unveiled by means of 1D- and 2D-NMR investigation. The different coordination ability and hydrogen bonding tendency of TFA– and OTf– led to specific interactions with the reaction partners dictating the regiodivergent outcome.
Item Type: | Article |
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Faculty \ School: | Faculty of Science > School of Chemistry |
Related URLs: | |
Depositing User: | LivePure Connector |
Date Deposited: | 19 Jun 2019 10:30 |
Last Modified: | 22 Oct 2022 04:51 |
URI: | https://ueaeprints.uea.ac.uk/id/eprint/71487 |
DOI: | 10.1021/acscatal.5b00502 |
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