Assessing the Role of Counterion in Gold-Catalyzed Dearomatization of Indoles with Allenamides by NMR Studies
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ToolsRocchigiani, Luca, Jia, Minqiang, Bandini, Marco and Macchioni, Alceo (2015) Assessing the Role of Counterion in Gold-Catalyzed Dearomatization of Indoles with Allenamides by NMR Studies. ACS Catalysis, 5 (7). pp. 3911-3915. ISSN 2155-5435
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Abstract
The counterion effect in the gold(I)-catalyzed dearomative condensation of indoles with allenamides is unveiled by means of 1D- and 2D-NMR investigation. The different coordination ability and hydrogen bonding tendency of TFA– and OTf– led to specific interactions with the reaction partners dictating the regiodivergent outcome.
| Item Type: | Article |
|---|---|
| Faculty \ School: | Faculty of Science > School of Chemistry |
| Related URLs: | |
| Depositing User: | LivePure Connector |
| Date Deposited: | 19 Jun 2019 10:30 |
| Last Modified: | 13 May 2021 13:46 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/71487 |
| DOI: | 10.1021/acscatal.5b00502 |
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