Iridium-EDTA as an efficient and readily available catalyst for water oxidation

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Savini, Adriana, Bellachioma, Gianfranco, Bolaño, Sandra, Rocchigiani, Luca, Zuccaccia, Cristiano, Zuccaccia, Daniele and Macchioni, Alceo (2012) Iridium-EDTA as an efficient and readily available catalyst for water oxidation. ChemSusChem, 5 (8). pp. 1415-1419. ISSN 1864-5631

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Abstract

It′s so easy: The readily available and highly water‐soluble [IrCl(Hedta)]Na complex is an efficient and robust catalyst for water oxidation to molecular oxygen. The reaction is driven by the reduction of Ce4+ to Ce3+. Its performances (TOF=6.8 min−1 and TON>12 000) are derived by UV/Vis spectroscopic, volumetric and electrochemical measurements, and compare favorably with those of the best catalysts reported so far.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Related URLs:	http://www.scopus.com/inward/record.url?...
Depositing User:	LivePure Connector
Date Deposited:	19 Jun 2019 07:30
Last Modified:	28 Mar 2025 09:23
URI:	https://ueaeprints.uea.ac.uk/id/eprint/71471
DOI:	10.1002/cssc.201200067

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