Iridium-EDTA as an efficient and readily available catalyst for water oxidation

Savini, Adriana, Bellachioma, Gianfranco, Bolaño, Sandra, Rocchigiani, Luca, Zuccaccia, Cristiano, Zuccaccia, Daniele and Macchioni, Alceo (2012) Iridium-EDTA as an efficient and readily available catalyst for water oxidation. ChemSusChem, 5 (8). pp. 1415-1419. ISSN 1864-5631

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Abstract

It′s so easy: The readily available and highly water‐soluble [IrCl(Hedta)]Na complex is an efficient and robust catalyst for water oxidation to molecular oxygen. The reaction is driven by the reduction of Ce4+ to Ce3+. Its performances (TOF=6.8 min−1 and TON>12 000) are derived by UV/Vis spectroscopic, volumetric and electrochemical measurements, and compare favorably with those of the best catalysts reported so far.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Related URLs:
Depositing User: LivePure Connector
Date Deposited: 19 Jun 2019 07:30
Last Modified: 22 Apr 2020 07:57
URI: https://ueaeprints.uea.ac.uk/id/eprint/71471
DOI: 10.1002/cssc.201200067

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