Self-aggregation tendency of zirconocenium ion pairs which model polymer-chain-carrying species in aromatic and aliphatic solvents with low polarity

Rocchigiani, L., Zuccaccia, C., Zuccaccia, D. and Macchioni, A. (2008) Self-aggregation tendency of zirconocenium ion pairs which model polymer-chain-carrying species in aromatic and aliphatic solvents with low polarity. Chemistry - A European Journal, 14 (22). ISSN 0947-6539

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Abstract

From pairs to double pairs: Zirconocene ion pairs bearing an aliphatic chain of variable length were synthesized and investigated by means of NOE and diffusion NMR spectroscopy experiments. The presence of long aliphatic chains allowed an unprecedented investigation of their self‐aggregation tendency in cyclohexane (see figure), which has a dielectric constant similar to that of isoparaffins used in industrial plants.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
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Depositing User: LivePure Connector
Date Deposited: 19 Jun 2019 06:32
Last Modified: 22 Apr 2020 07:57
URI: https://ueaeprints.uea.ac.uk/id/eprint/71465
DOI: 10.1002/chem.200800818

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