Hierarchical chestnut-like MnCo2O4 nanoneedles grown on nickel foam as binder-free electrode for high energy density asymmetric supercapacitors

Hui, Kwun Nam, Hui, Kwan San, Tang, Zikang, Jadhav, V.V. and Xia, Qi Xun (2016) Hierarchical chestnut-like MnCo2O4 nanoneedles grown on nickel foam as binder-free electrode for high energy density asymmetric supercapacitors. Journal of Power Sources, 330. 195–203. ISSN 0378-7753

[img]
Preview
PDF (Accepted manuscript) - Submitted Version
Available under License Creative Commons Attribution Non-commercial No Derivatives.

Download (1MB) | Preview

Abstract

Hierarchical chestnut-like manganese cobalt oxide (MnCo2O4) nanoneedles (NNs) are successfully grown on nickel foam using a facile and cost-effective hydrothermal method. High resolution TEM image further verifies that the chestnut-like MnCo2O4 structure is assembled by numerous 1D MnCo2O4 nanoneedles, which are formed by numerous interconnected MnCo2O4 nanoparticles with grain diameter of ∼10 nm. The MnCo2O4 electrode exhibits high specific capacitance of 1535 F g−1 at 1 A g−1 and good rate capability (950 F g−1 at 10 A g−1) in a 6 M KOH electrolyte. An asymmetric supercapacitor is fabricated using MnCo2O4 NNs on Ni foam (MnCo2O4 NNs/NF) as the positive electrode and graphene/NF as the negative electrode. The device shows an operation voltage of 1.5 V and delivers a high energy density of ∼60.4 Wh kg−1 at a power density of ∼375 W kg−1. Moreover, the device exhibits an excellent cycling stability of 94.3% capacitance retention after 12000 cycles at 30 A g−1. This work demonstrates that hierarchical chestnut-like MnCo2O4 NNs could be a promising electrode for the high performance energy storage devices.

Item Type: Article
Uncontrolled Keywords: mnco2o4,nanoneedles,graphene,hydrothermal,asymmetric supercapacitor
Faculty \ School: Faculty of Science > School of Mathematics
Depositing User: Pure Connector
Date Deposited: 10 Nov 2016 10:00
Last Modified: 24 Nov 2020 00:59
URI: https://ueaeprints.uea.ac.uk/id/eprint/61301
DOI: 10.1016/j.jpowsour.2016.08.116

Actions (login required)

View Item View Item