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Hui, K. N., Hui, K. S. 
ORCID: https://orcid.org/0000-0001-7089-7587, Zhang, X. L., Mane, Rajaram S. and Naushad, Mu.
(2016)
Photosensitization of ZnO nanowire-based electrodes using one-step hydrothermally synthesized CdSe/CdS (core/shell) sensitizer.
Solar Energy, 125.
pp. 125-134.
ISSN 0038-092X
Abstract
One-step assembled CdSe/CdS (core/shell) quantum dots (QDs) were deposited onto ZnO nanowires (NWs) and characterized for their structure, morphology and optical analyses. As deposited ZnO NWs array were wurtzite in structure. During a single hydrothermal cycle a layer of ~4nm CdSe/CdS QDs was formed onto ZnO NWs and overgrowth evidenced with an additional 2-5 layers due to which, (a) absorbance density, and (b) Raman Shift of 1LO mode (from 286cm-1 to 296cm-1) increased and (c) the photoluminescence intensity of the near band-edge emission peak at ~379nm decreased. Due to more accumulation of CdSe/CdS, photoelectrochemical cells of ZnO-based photoelectrodes designed for 1-4 cycles of CdSe/CdS onto indium-tin-oxide substrate demonstrated increasing power conversion efficiency trend from 0.18% to 1.29% whereas, for 5th cycle power conversion efficiency, due to an increased series resistance, decreased to 1.12% on account of an accumulation of several QDs.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | cds at cdse,morphology,photoelectrochemical cells,photoluminescence,structure |
| Faculty \ School: | Faculty of Science > School of Engineering University of East Anglia Research Groups/Centres > Theme - ClimateUEA |
| UEA Research Groups: | Faculty of Science > Research Groups > Energy Materials Laboratory Faculty of Science > Research Groups > Emerging Technologies for Electric Vehicles (EV) |
| Related URLs: | |
| Depositing User: | Pure Connector |
| Date Deposited: | 09 Nov 2016 16:00 |
| Last Modified: | 20 Apr 2023 00:15 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/61297 |
| DOI: | 10.1016/j.solener.2015.12.002 |
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