Self-sustained combustion of carbon monoxide promoted by the Cu-Ce/ZSM-5 catalyst in CO/O2/N2 atmosphere

Bin, Feng, Wei, Xiaolin, Li, Bo and Hui, Kwan San ORCID: https://orcid.org/0000-0001-7089-7587 (2015) Self-sustained combustion of carbon monoxide promoted by the Cu-Ce/ZSM-5 catalyst in CO/O2/N2 atmosphere. Applied Catalysis B: Environmental, 162. pp. 282-288. ISSN 0926-3373

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Abstract

The Cu/ZSM-5, Ce/ZSM-5 and Cu-Ce/ZSM-5 catalysts were prepared and characterized in this investigation and the catalytic activity of carbon monoxide (CO) combustion under these catalysts was determined by temperature-programmed oxidation. The activity for the CO combustion follows the decreasing order: Cu-Ce/ZSM-5>Cu/ZSM-5>Ce/ZSM-5, indicated by lower ignition, light-off, extinction temperature and broader hysteresis determined via both heating and cooling feeding process. The CO adsorbed on the copper sites to form Cu+-CO complexes, monodentate and bidentate carbonates was considered to be the crucial step for CO catalytic combustion. At the CO concentration ≥5vol.%, the CO self-sustained combustion was achieved over the Cu-Ce/ZSM-5 catalyst. One reason is due to formation of Cu2+ ions incorporated into cerium oxides, which are more reducible than the copper clusters, minicrystals and bulk CuO particles. Another reason is attributable to the formation of Ce4+/Ce3+ redox couple, which facilitates oxygen transport on the catalyst surface.

Item Type:	Article
Uncontrolled Keywords:	carbon monoxide,catalytic activity,zsm-5,self-sustained combustion
Faculty \ School:	Faculty of Science > School of Mathematics
Related URLs:	http://www.scopus.com/inward/record.url?...
Depositing User:	Pure Connector
Date Deposited:	24 Sep 2016 00:54
Last Modified:	21 Oct 2022 06:33
URI:	https://ueaeprints.uea.ac.uk/id/eprint/60260
DOI:	10.1016/j.apcatb.2014.07.007

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