Metallocene to metallocene conversion. Synthesis of an oxazoline-substituted pentamethyliridocenium cation from a ferrocenyloxazoline

Arthurs, Ross A., Horton, Peter N., Coles, Simon J. and Richards, Christopher J. ORCID: https://orcid.org/0000-0001-7899-4082 (2016) Metallocene to metallocene conversion. Synthesis of an oxazoline-substituted pentamethyliridocenium cation from a ferrocenyloxazoline. Chemical Communications, 52 (43). pp. 7024-7027. ISSN 1359-7345

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Abstract

Reaction of (S)-2-ferrocenyl-4-(1-methylethyl)oxazoline with [(CpIrCl2)-Ir-star](2) in benzonitrile with KPF6 and NaOH gave (eta(5)-(S)-2-(4-(1-methylethyl))oxazolinylcyclopentadienyl)(eta(5)-pentamethylcyclopentadienyl)-iridium(III) hexafluorophosphate (68%). This transformation of an iron-based into an iridium-based metallocene proceeds via the rearrangement, with loss of cyclopentadienyliron, of an intermediate cationic ferrocenyliridacycle.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry Faculty of Science
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User:	Pure Connector
Date Deposited:	23 Sep 2016 23:58
Last Modified:	22 Oct 2022 01:18
URI:	https://ueaeprints.uea.ac.uk/id/eprint/59751
DOI:	10.1039/c6cc01959e

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