Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence

Romanov, Alexander S., Di, Dawei, Yang, Le, Fernandez-Cestau, Julio, Becker, Ciaran R., James, Charlotte E., Zhu, Bonan, Linnolahti, Mikko, Credgington, Dan and Bochmann, Manfred (2016) Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence. Chemical Communications, 52 (38). pp. 6379-6382. ISSN 1359-7345

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Abstract

Linear two-coordinate copper complexes of cyclic (alkyl)(amino)-carbenes (CAAC)CuX (X = halide) show photoluminescence with solid-state quantum yields of up to 96%; in contrast to previously reported Cu photoemitters the emission is independent of temperature over the range T = 4 – 300 K and occurs very efficiently by prompt rather than delayed fluorescence, with lifetimes in the sub-nanosecond range.

Item Type: Article
Additional Information: Correction available at dx.doi.org/10.1039/C8CC90135J
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Pure Connector
Date Deposited: 27 May 2016 12:00
Last Modified: 29 Jun 2020 23:47
URI: https://ueaeprints.uea.ac.uk/id/eprint/59105
DOI: 10.1039/C6CC02349E

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