Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence
Romanov, Alexander S., Di, Dawei, Yang, Le, Fernandez-Cestau, Julio, Becker, Ciaran R., James, Charlotte E., Zhu, Bonan, Linnolahti, Mikko, Credgington, Dan and Bochmann, Manfred (2016) Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence. Chemical Communications, 52 (38). pp. 6379-6382. ISSN 1359-7345
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Abstract
Linear two-coordinate copper complexes of cyclic (alkyl)(amino)-carbenes (CAAC)CuX (X = halide) show photoluminescence with solid-state quantum yields of up to 96%; in contrast to previously reported Cu photoemitters the emission is independent of temperature over the range T = 4 – 300 K and occurs very efficiently by prompt rather than delayed fluorescence, with lifetimes in the sub-nanosecond range.
Item Type: | Article |
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Additional Information: | Correction available at dx.doi.org/10.1039/C8CC90135J |
Faculty \ School: | Faculty of Science > School of Chemistry |
Depositing User: | Pure Connector |
Date Deposited: | 27 May 2016 12:00 |
Last Modified: | 25 Jan 2021 00:46 |
URI: | https://ueaeprints.uea.ac.uk/id/eprint/59105 |
DOI: | 10.1039/C6CC02349E |
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