Al-Yasari, Ahmed ORCID: https://orcid.org/0000-0001-8768-1248, Van Steerteghem, Nick, El Moll, Hani, Clays, Koen and Fielden, John ORCID: https://orcid.org/0000-0001-5963-7792 (2016) Donor–acceptor organo-imido polyoxometalates: high transparency, high activity redox-active NLO chromophores. Dalton Transactions, 45 (7). pp. 2818-2822. ISSN 1477-9226
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Abstract
We show that polyoxometalates (POMs) are an excellent redox-active acceptor on which to base high performance 2nd order non-linear optical (NLO) chromophores. This is demonstrated through three new organoimido-Lindqvist derivatives with HRS β0-values exceeding those of any dipolar organic system with comparable donor, π-system and absorption profile. Thus, organoimido POMs may provide a new generation of high performance, high transparency, and potentially redox-switchable NLO materials.
Item Type: | Article |
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Additional Information: | This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. |
Faculty \ School: | Faculty of Science > School of Chemistry (former - to 2024) Faculty of Science |
UEA Research Groups: | Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Energy Materials Laboratory |
Depositing User: | Pure Connector |
Date Deposited: | 18 Feb 2016 11:00 |
Last Modified: | 24 Sep 2024 11:33 |
URI: | https://ueaeprints.uea.ac.uk/id/eprint/57165 |
DOI: | 10.1039/C6DT00115G |
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