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Rosca, Dragos-Adrian, Fernandez Cestau, Julio, Hughes, David L. and Bochmann, Manfred 
ORCID: https://orcid.org/0000-0001-7736-5428
(2015)
Reactivity of Gold Hydrides: O2 Insertion into the Au–H Bond.
Organometallics, 34 (11).
2098−2101.
ISSN 0276-7333
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Abstract
Dioxygen reacts with the gold(I) hydride (IPr)AuH under insertion to give the hydroperoxide, (IPr)AuOOH, a long-postulated reaction in gold catalysis and the first demonstration of O2 activation by Au-H in a well-defined system. Subsequent condensation gave the peroxide (IPr)Au-OO-Au(IPr) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazole-2-ylidene). The reaction kinetics are reported, as well as the reactivity of Au(I) hydrides with radical scavengers.
| Item Type: | Article |
|---|---|
| Additional Information: | ACS AuthorChoice - This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
| Faculty \ School: | Faculty of Science > School of Chemistry |
| UEA Research Groups: | Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Chemistry of Materials and Catalysis |
| Depositing User: | Pure Connector |
| Date Deposited: | 21 Jan 2016 12:00 |
| Last Modified: | 22 Oct 2022 00:33 |
| URI: | https://ueaeprints.uea.ac.uk/id/eprint/56721 |
| DOI: | 10.1021/om501165z |
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