First examples of functionalisation of meso-aryl tetrabenzotriazaporphyrins (TBTAPs) through cross-coupling reactions

Alharbi, Nuha, Tizzard, Graham J., Coles, S. J., Cook, Mike and Cammidge, Andy (2015) First examples of functionalisation of meso-aryl tetrabenzotriazaporphyrins (TBTAPs) through cross-coupling reactions. Tetrahedron, 71 (39). 7227–7232. ISSN 0040-4020

[img]
Preview
PDF (KATRITZKY TBTAP TETRAHEDRON 2015 FINAL) - Submitted Version
Available under License Creative Commons Attribution Non-commercial No Derivatives.

Download (200kB) | Preview

Abstract

Recent synthetic advances have given convenient access to tetrabenzotriazaporphyrins (TBTAPs) functionalised with meso-aryl substituents. In this paper we report the first examples of further functionalization of the meso-sites through Suzuki-Miyaura and copper-free Sonagashira cross-coupling reactions of the meso-(bromophenyl)TBTAPs, demonstrating the breadth of new materials design now possible in the hybrid macrocycles.

Item Type: Article
Uncontrolled Keywords: phthalocyanines,porphyrins,heterocycles,synthesis,hybrids,cross-coupling
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Pure Connector
Date Deposited: 24 Jul 2015 22:11
Last Modified: 22 Apr 2020 00:03
URI: https://ueaeprints.uea.ac.uk/id/eprint/53549
DOI: 10.1016/j.tet.2015.03.095

Actions (login required)

View Item View Item