Signatures of material and optical chirality:Origins and measures

Bradshaw, David S., Leeder, Jamie M., Coles, Matthew and Andrews, David L. (2015) Signatures of material and optical chirality:Origins and measures. Chemical Physics Letters, 626. 106–110. ISSN 0009-2614

[img]
Preview
PDF (Bradshaw_et_al_2015_ChemPhysLett) - Published Version
Available under License Creative Commons Attribution.

Download (1MB) | Preview

Abstract

Chirality in materials and light is of abiding interest across a broad range of scientific disciplines. This article discusses present and emerging issues in relation to molecular and optical chirality, also including some important developments in chiral metamaterials. Quantifying the chirality of matter or light leads to issues concerning the most appropriate measures, such as a helicity parameter for specific chiral chromophores and technical measures of light chirality. An optical helicity and chirality density depend on a difference between the numbers of left- and right-handed photons in a beam. In connection with circularly polarized luminescence, adoption of the Stokes parameter to spontaneous emission from chiral molecules invites critical attention. Modern spectroscopic techniques are often based on the different response arising from left-handed circularly polarized light compared to right-handed light. This dissimilarity can be exploited as a foundation for the separation of chiral molecules, promising new avenues of application.

Item Type: Article
Additional Information: Under a Creative Commons Attribution (CC BY) licence.
Faculty \ School: Faculty of Science > School of Chemistry
Faculty of Science > School of Mathematics
Faculty of Science
Related URLs:
Depositing User: Pure Connector
Date Deposited: 08 Apr 2015 15:48
Last Modified: 27 May 2020 23:50
URI: https://ueaeprints.uea.ac.uk/id/eprint/53100
DOI: 10.1016/j.cplett.2015.02.051

Actions (login required)

View Item View Item