The fate of NOx emissions due to nocturnal oxidation at high latitudes: 1-D simulations and sensitivity experiments

Joyce, P. L., Von Glasow, R. and Simpson, W. R. (2014) The fate of NOx emissions due to nocturnal oxidation at high latitudes: 1-D simulations and sensitivity experiments. Atmospheric Chemistry and Physics, 14. pp. 7601-7616. ISSN 1680-7324

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Abstract

The fate of nitrogen oxide pollution during high-latitude winter is controlled by reactions of dinitrogen pentoxide (N2O5) and is highly affected by the competition between heterogeneous atmospheric reactions and deposition to the snowpack. MISTRA (MIcrophysical STRAtus), a 1-D photochemical model, simulated an urban pollution plume from Fairbanks, Alaska to investigate this competition of N2O5 reactions and explore sensitivity to model parameters. It was found that dry deposition of N2O5 made up a significant fraction of N2O5 loss near the snowpack, but reactions on aerosol particles dominated loss of N2O5 over the integrated atmospheric column. Sensitivity experiments found the fate of NOx emissions were most sensitive to NO emission flux, photolysis rates, and ambient temperature. The results indicate a strong sensitivity to urban area density, season and clouds, and temperature, implying a strong sensitivity of the results to urban planning and climate change. Results suggest that secondary formation of particulate (PM2.5) nitrate in the Fairbanks downtown area does not contribute significant mass to the total PM2.5 concentration, but appreciable amounts are formed downwind of downtown due to nocturnal NOx oxidation and subsequent reaction with ammonia on aerosol particles.

Item Type: Article
Additional Information: © Author(s) 2014. This work is distributed under the Creative Commons Attribution 3.0 License.
Faculty \ School: Faculty of Science > School of Environmental Sciences
Depositing User: Pure Connector
Date Deposited: 21 Aug 2014 08:50
Last Modified: 24 Jul 2019 20:14
URI: https://ueaeprints.uea.ac.uk/id/eprint/49959
DOI: 10.5194/acp-14-7601-2014

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