Pentametallic lanthanide-alkoxide square-based pyramids: high energy barrier for thermal relaxation in a holmium single molecule magnet

Blagg, Robin J., Tuna, Floriana, McInnes, Eric J. L. and Winpenny, Richard E. P. (2011) Pentametallic lanthanide-alkoxide square-based pyramids: high energy barrier for thermal relaxation in a holmium single molecule magnet. Chemical Communications, 47 (38). pp. 10587-10589. ISSN 1359-7345

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Abstract

Pentametallic Ln complexes of formula [Ln5O(OiPr)13] have been made, where LnIII = Sm, Gd, Tb, Ho and Er; slow magnetisation relaxation to 33 K is observed for the Ho complex with an energy barrier of ca. 400 K.

Item Type: Article
Faculty \ School: Faculty of Science > School of Chemistry
Depositing User: Pure Connector
Date Deposited: 14 Mar 2014 12:30
Last Modified: 21 Apr 2020 22:56
URI: https://ueaeprints.uea.ac.uk/id/eprint/48127
DOI: 10.1039/c1cc14186d

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