Diastereoselective synthesis of half-sandwich chiral-at-metal cobaltacycles by oxidative cyclisation

Amin, Jahangir and Richards, Christopher J. (2012) Diastereoselective synthesis of half-sandwich chiral-at-metal cobaltacycles by oxidative cyclisation. Chemical Communications, 48 (82). pp. 10192-10194. ISSN 1359-7345

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Abstract

Reaction of chiral ester linked diynes with chlorotris(triphenylphosphine)cobalt(I) and sodium cyclopentadienide gave (?5-cyclopentadienyl)(triphenylphosphine) cobaltacyclopentadiene complexes as single chiral-at-metal diastereoisomers, including a non-racemic example synthesised in three steps from (S)-3-butyn-2-ol.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Synthetic Chemistry (former - to 2017) Faculty of Science > Research Groups > Chemistry of Materials and Catalysis
Depositing User:	Rachel Smith
Date Deposited:	12 Apr 2013 20:22
Last Modified:	28 Mar 2025 02:32
URI:	https://ueaeprints.uea.ac.uk/id/eprint/42016
DOI:	10.1039/C2CC34837C

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