A fluorophosphate-based inverse Keggin structure

Fielden, John, Quasdorf, Kyle, Cronin, Leroy and Kögerler, Paul (2012) A fluorophosphate-based inverse Keggin structure. Dalton Transactions, 41 (33). pp. 9876-9878. ISSN 1477-9226

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Abstract

An unusual PFO32−-templated “inverse Keggin” polyanion, [Mo12O46(PF)4]4−, has been isolated from the degradation reaction of an {Mo132}-type Keplerate to [PMo12O40]3− by [Cu(MeCN)4](PF6) in acetonitrile. 31P-NMR studies suggest a structure-directing role for [Cu(MeCN)4]+ in the formation of the highly unusual all-inorganic inverse Keggin structure.

Item Type:	Article
Faculty \ School:	Faculty of Science > School of Chemistry (former - to 2024)
UEA Research Groups:	Faculty of Science > Research Groups > Chemistry of Materials and Catalysis Faculty of Science > Research Groups > Chemistry of Light and Energy Faculty of Science > Research Groups > Energy Materials Laboratory
Depositing User:	Users 2731 not found.
Date Deposited:	17 Oct 2012 08:54
Last Modified:	28 Mar 2025 02:34
URI:	https://ueaeprints.uea.ac.uk/id/eprint/39939
DOI:	10.1039/c2dt30501a

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